Product ID:DIPHENYLCARBAZONE REAGENT, SHALES AND SHALES (SUPDAT)
MSDS Date:08/05/1987
FSC:6810
NIIN:00N058810
MSDS Number: BXFLR

ANDERSON LABORATORIES INC

5901 FITZHUGH AVENUE
FORT WORTH, TX 76119
US

Emergency Phone: 800-424-9300(CHEMTREC)

Info Phone: 817-457-4474

Cage: 0E6V4

ANDERSON LABORATORIES INC

FORT WORTH, TX 76119 US

Telephone: 817-457-4474

Cage: 0E6V4

(ORAL,RAT) 7060

CAS: 64-17-5

RTECS: KQ6300000

Fraction By Weight: 95% V/V

OSHA PEL 1000 PPM

ACGIH TLV: 1000 PPM

36%.

CAS: 67-56-1

RTECS: PC1400000

Fraction By Weight: 5% V/V

OSHA PEL 200 PPM, S

ACGIH TLV: 200 PPM;250 STEL, S

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:SEE INGREDIENTS.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE:PROLONGED EXPOSURE TO EXCESSIVE
CONCENTRATIONS OF ETHANOL MAY RESULT IN IRRITATION OF MUCOUS
MEMBRANES, HEADACHE, DROWSINESS, FATIGUE & NARCOSIS. METHANOL IS
ALSO NARCOTIC IN EFFECT & ITS EFFECT S ARE CUMULATIVE. OVEREXPOSURE
TO METHANOL CAN RESULT IN ACIDOSIS & VISUAL DISTURBANCES WHICH MAY
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ:PROGRESS TO PERMANENT LOSS OF VISION.
CHRONIC:NERVOUS SYSTEM DISTURBANCES, NARCOSIS, LIVER DAMAGE. TARGET
ORGANS:SKIN, EYES, LIVER, CENTRAL NERVOUS SYSTEM.
Medical Cond Aggravated by Exposure:NOT KNOWN.

First Aid:INGEST:INDUCE VOMIT BY GIVING SYRUP OF IPECAC/BY STICKING
FINGER DOWN THROAT. NEVER GIVE ANYTHING BY MOUTH TO UNCON PERS.
CALL MD. EYES:IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MINS.
SKIN:IMMED FLU SH W/PLENTY OF WATER FOR AT LST 15 MINSWHILE
REMOVING CONTAM CLTHG & SHOES. WASH CLTHG & THORO CLEAN SHOES
BEFORE REUSE. IF SHOES ARE CONTAM, DESTROY. INHAL:REMOVE TO FRESH
AIR. IF NOT BRTHG,(SUPDAT)

Flash Point Method:OC
Flash Point:58.0F,14.4C
Lower Limits:SEE ING 1
Upper Limits:SEE ING 2
Extinguishing Media:FOAM, ALCOHOL FOAM, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:USE NIOSH/MSHA APPROVED SCBA & FULL PROTECTIVE
EQUIPMENT .
Unusual Fire/Explosion Hazard:VAPORS ARE HVR/AIR & MAY TRAVEL ALONG THE
GROUND OR MAY BE MOVED BY VENTILATION TO AN IGNITION SOURCE & FLASH
BACK.

Spill Release Procedures:SHUT OFF ALL SOURCES OF IGNITION. ABSORB OR
COVER W/SAND OR VERMICULITE. CAREFULLY PICK UP & PLACE IN CLOSED
CONTAINER FOR DISPOSAL I/A/W LOCAL, STATE & FEDERAL REGULATIONS.
FLUSH SPILL AREA W/COPIOUS AMOUNTS OF WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:DO NOT STORE/USE NEAR HEAT, SPARKS OR
FLAME. STORE ONLY IN WELL VENTILATED AREAS. DO NOT GET IN EYES.
AVOID SKIN CONTACT. CANNOT BE MADE NONPOISONOUS.
Other Precautions:FLAMM LIQUID. CAUTION! PRODUCT RESIDUE MAY REMAIN ON
OR IN "EMPTY" PACKAGE. ALL PRECS FOR HNDLG PROD MUST BE USED IN
HNDLG EMPTY PACKAGE & RESIDUE. DANGER! CAN BE FATAL IF SWALLOWED.
WARNING! HARMFUL IF INHALED/ABSORBED THRU SKIN. (SUPDAT)

Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATOR APPROPRIATE FOR
EXPOSURE OF CONCERN . NOT APPLICABLE FOR LABORATORY SIZE
QUANTITIES.
Ventilation:MECHANICAL VENTILATION (AT LEAST 10 AIR CHANGES PER HOUR
PER ROOM).
Protective Gloves:LATEX GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:EYE WASH FOUNTAIN & DELUGE SHOWER WHICH MEET
ANSI DESIGN CRITERIA . APRON.
Work Hygienic Practices:WASH HANDS THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health
MFR'S TRADE NAME/PART NO:FOR CHLORIDE. FIRST AID PROC:GIVE ARTF RESP,
PREF MOUTH TO MOUTH. IF BRTHG IS DFCLT, GIVE OXYGEN. CALL MD. OTHER
PREC:CAUSES SKIN & EYE IRRIT. DO NOT EAT, DRINK/SMOKE WHILE HN DLG.
DO NOT HANDLE UNTIL MFR'S SAFETY PRECS HAVE BEEN READ & UNDERSTOOD.

Boiling Pt:B.P. Text:172F,78C
Vapor Pres:44 @ 20C
Vapor Density:HVR/AIR
Spec Gravity:LTR/WTR
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:DARK COLORED LIQUID W/CHARACTERISTIC ODOR.

Stability Indicator/Materials to Avoid:YES
OXIDIZING MATERIALS CAN CAUSE A VIGOROUS REACTION.
Stability Condition to Avoid:EXTREME HEAT & OPEN FLAME.
Hazardous Decomposition Products:AS W/ANY OTHER ORGANIC MATERIAL,
COMBUSTION WILL PRODUCE CARBON DIOXIDE & PROBABLY CARBON MONOXIDE.

Waste Disposal Methods:DISPOSAL MUST BE I/A/W FEDERAL, STATE & LOCAL
REGULATIONS .

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.